| August 2025Aug 15 |  LaLiga | Villarreal 2–0 OviedoRegular Season - 1 | W |
| Aug 24 | LaLiga | Villarreal5–0 GironaRegular Season - 2 | W |
| Aug 31 | LaLiga | Celta Vigo 1–1VillarrealRegular Season - 3 | D |
| September 2025Sep 13 | LaLiga | Atletico Madrid 2–0VillarrealRegular Season - 4 | L |
| Sep 16 |  Champions League | Tottenham 1–0VillarrealLeague Stage - 1 | L |
| Sep 20 | LaLiga | Villarreal2–1 OsasunaRegular Season - 5 | W |
| Sep 23 | LaLiga | Sevilla 1–2VillarrealRegular Season - 6 | W |
| Sep 27 | LaLiga | Villarreal1–0 Athletic ClubRegular Season - 7 | W |
| October 2025Oct 01 | Champions League | Villarreal2–2 JuventusLeague Stage - 2 | D |
| Oct 04 | LaLiga | Real Madrid 3–1VillarrealRegular Season - 8 | L |
| Oct 18 | LaLiga | Villarreal2–2 Real BetisRegular Season - 9 | D |
| Oct 21 | Champions League | Villarreal0–2 Manchester CityLeague Stage - 3 | L |
| Oct 25 | LaLiga | Valencia 0–2VillarrealRegular Season - 10 | W |
| November 2025Nov 01 | LaLiga | Villarreal4–0 Rayo VallecanoRegular Season - 11 | W |
| Nov 05 | Champions League | Pafos 1–0VillarrealLeague Stage - 4 | L |
| Nov 08 | LaLiga | Espanyol 0–2VillarrealRegular Season - 12 | W |
| Nov 22 | LaLiga | Villarreal2–1 MallorcaRegular Season - 13 | W |
| Nov 25 | Champions League | Borussia Dortmund 4–0VillarrealLeague Stage - 5 | L |
| Nov 30 | LaLiga | Real Sociedad 2–3VillarrealRegular Season - 14 | W |
| December 2025Dec 06 | LaLiga | Villarreal2–0 GetafeRegular Season - 15 | W |
| Dec 10 | Champions League | Villarreal2–3 FC CopenhagenLeague Stage - 6 | L |
| Dec 21 | LaLiga | Villarreal0–2 BarcelonaRegular Season - 17 | L |
| January 2026Jan 03 | LaLiga | Elche 1–3VillarrealRegular Season - 18 | W |
| Jan 10 | LaLiga | Villarreal3–1 AlavesRegular Season - 19 | W |
| Jan 17 | LaLiga | Real Betis2–0VillarrealRegular Season - 20 | L |
| Jan 20 | Champions League | Villarreal1–2 AjaxLeague Stage - 7 | L |
| Jan 24 | LaLiga | Villarreal0–2Real MadridRegular Season - 21 | L |
| Jan 28 | Champions League | Bayer Leverkusen 3–0VillarrealLeague Stage - 8 | L |
| Jan 31 | LaLiga | Osasuna2–2VillarrealRegular Season - 22 | D |
| February 2026Feb 09 | LaLiga | Villarreal4–1EspanyolRegular Season - 23 | W |
| Feb 14 | LaLiga | Getafe2–1VillarrealRegular Season - 24 | L |
| Feb 18 | LaLiga | Levante 0–1VillarrealRegular Season - 16 | W |
| Feb 22 | LaLiga | Villarreal2–1ValenciaRegular Season - 25 | W |
| Feb 28 | LaLiga | Barcelona4–1VillarrealRegular Season - 26 | L |
| March 2026Mar 08 | LaLiga | Villarreal2–1ElcheRegular Season - 27 | W |
| Mar 13 | LaLiga | Alaves1–1VillarrealRegular Season - 28 | D |
| Mar 20 | LaLiga | Villarreal3–1Real SociedadRegular Season - 29 | W |
| April 2026Apr 06 | LaLiga | Girona1–0VillarrealRegular Season - 30 | L |
| Apr 12 | LaLiga | Athletic Club1–2VillarrealRegular Season - 31 | W |
| Apr 23 | LaLiga | Oviedo1–1VillarrealRegular Season - 33 | D |
| Apr 26 | LaLiga | Villarreal2–1Celta VigoRegular Season - 32 | W |
| May 2026May 02 | LaLiga | Villarreal5–1LevanteRegular Season - 34 | W |
| May 10 | LaLiga | Mallorca1–1VillarrealRegular Season - 35 | D |
| May 13 | LaLiga | Villarreal2–3SevillaRegular Season - 36 | L |
| May 17 | LaLiga | Rayo Vallecano2–0VillarrealRegular Season - 37 | L |
| May 24 | LaLiga | Villarreal5–1Atletico MadridRegular Season - 38 | W |
